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7th August The Hindu ePaper

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What is shale gas? How is it produced? Why are we talking about it?

Shale trail

Boondoggle. That’s how Dick Martin explained to me the shale gas revolution in the United States of America. Boondoggle is a slang for an activity that is wasteful or pointless but gives the appearance of having value. Martin, a 70 years old US Army veteran, works with Pennsylvania Forest Coalition that is raising the awareness of people about the negative impacts of shale gas drilling in forests. Martin was driving me to Loyalsock State Forest, about 300 km from Pittsburgh, where shale gas is being developed on a massive scale.

Pennsylvania’s history has been filled with natural resources booms and busts. Timber was the first resource to be extracted. It devastated the forests. The first large-scale coal mines of the US were opened in Pennsylvania. The first oil wells were drilled there. The US’ first nuclear power plant opened there. The worst commercial nuclear accident occurred in Pennsylvania in 1979. During all these resource booms, industry made money and then walked away. It is estimated that the state has more than 200,000 exhausted gas and oil wells which companies have abandoned without plugging. In between these booms and busts, this largely agricultural state has struggled economically. Shale gas is the newest natural resource that the state has put its eyes on.

Pennsylvania is at the heart of the shale gas development in the US. It sits above three formations of shale, named Marcellus, Devonian and Utica, which contain some of the world’s largest shale gas reserves. The current proven reserve is estimated to be 44 trillion cubic feet (tcf), which is similar to natural gas reserves in India. But unlike India, every year Pennsylvania’s reserves are being revised upwardly.


It was in the late 1990s that techniques to economically extract the gas from shale formations were developed. In mid-2000, the political establishment in Pennsylvania saw shale gas as a way to generate employment and boost local economies, and embraced gas drilling like a modern gold rush. The results have been startling.

From 2005 till March 2014, permits were issued to drill 13,793 wells and 7,618 wells have been drilled. Production of shale gas has soared from 1 billion cubic feet in 2008 to 4.0 tcf in 2014. To give an idea of the scale, India’s total natural gas output in 2013-14 was less than one-third of Pennsylvania’s and one-tenth of US shale gas production.

Shale gas development in Pennsylvania started in state forests as the state government opened huge public forestland for it. Forests in Pennsylvania are also split estates in which the sub-surface mineral rights are vested with private individuals or companies, while the surface rights are vested with the state. In these estates, the government can do nothing to stop shale gas drilling. As a result, of the 890,000 hectares (ha) of state forests, nearly 280,000 ha have been made available for fracking and leases have been issued on 156,000 ha. Most of these are private leases. In the remaining, however, the state is making a lot of money as lease rent, taxes and royalty. But this money is coming at a huge ecological cost.


As Martin and I moved from one part of the Loyalsock State Forest to another, I saw how unplanned shale gas development was fragmenting the forest and damaging the ecology. It resembled the Wild West. There is no plan and hardly any coordination between agencies. Companies have drilled wherever it suited them. Each has separate roads and pipelines to carry water and shale gas even in the same area. Instead of transporting gas through pipelines in a predefined direction—for instance, along the roads—gas is being transported in multiple directions. Such an extensive fragmentation could have devastating implications for the forest’s ecology, but I didn’t get a sense if people cared. And I understood why.

As I saw more shale gas pads, I also grew ambivalent towards shale. At every site a few hectares of forest area was clear-cut and on a concrete pad 6-12 wells were producing gas silently. No pollution was visible. A tank was collecting wastewater coming out of the wells. The sites looked much neater and cleaner than the conventional oil and gas wells I had seen in India.

To a citizen of Pennsylvania an individual shale gas site may not give any impression of negative environmental impact. On top of it, shale drilling has bought down the prices of natural gas to historically low levels (see ‘Revolution’). This is why I found that even Dick had no problems with shale gas, only with the haphazard manner in which it was being done.

But I soon realised that shale gas is different. When Martin showed me the aerial shots of the forest area, it struck me that a large number of shale gas pads had been gouged in a very small area. This is in stark contrast with conventional gas extraction.

Shale v conventional gas

Shale gas is less concentrated than conventional deposits. It is trapped in low permeability rocks that impede its flow, requiring more invasive drilling and production activities. Whereas onshore conventional fields might require less than one well per 10 square kilometres (km2), shale fields might need more than 10. In addition to the smaller recoverable hydrocarbon content per unit of land, shale gas development tends to extend across a much larger geographic area, thereby affecting a larger population.

Marcellus Shale in the US, for example, covers more than 250,000 km2, which is about 10 times the Hugoton Natural Gas Area in Kansas, the country’s largest conventional gas-producing zone.

Another difference between shale gas and conventional gas is hydraulic fracturing or fracking. In this water mixed with chemicals is pumped into the ground to create cracks in shale rock to release the gas (see ‘ABC of shale gas’,). While some of the conventional wells are also fracked to increase output, all shale wells must be fracked to release gas. This means shale gas production requires lots of water and chemicals and, therefore, generates a lot more waste. Shale gas, therefore, has a substantially higher environmental impact than conventional gas.

“Water contamination with shale gas is an engineering problem and not a foregone conclusion”

Scott Perry, Deputy secretary, Department of Environment Protection, Pennsylvania
Water, waste and more

Compared to conventional gas, shale gas requires 2,000 to 10,000 times more water. A single shale well may require a few thousands cubic metres (m3) to 20,000 m3 of water. Across the US, about 170 million m3 of water was used annually to hydraulically fracture 25,000-30,000 new wells. This is equivalent to providing 100 litres of water every day to about 4.5 million people. The vast majority of water used was fresh; only about 5 per cent was reuse of wastewater. In some of the counties in the US, annual hydraulic fracturing water use even exceeded 50 per cent of the counties’ total water use. In water-scarce areas, including shale gas basins like Cauvery and Damodar in India, shale gas extraction can have serious environmental and social impacts. Water is the single most important factor for shale gas development anywhere.

Fracking can pollute groundwater as well as rivers and streams. In the US, leaks and spills of chemicals from fracking sites have been widely reported. More than 1,000 complaints of drinking water contamination due to fracking have been documented.

A study by researchers at Duke University found that the proximity of drinking water wells to fracking wells increases the risk of contamination of water with methane in Pennsylvania. Faulty well casing was found to be the main cause. Well casing is the larger diameter pipe that is inserted in the borehole and kept in place with cement. Because of the high-pressure injection, shale gas is more likely to have problems with structural integrity than a conventional well. Data from Pennsylvania shows that a shale well is six times more likely to have casing failure than a conventional well.

I asked Scott Perry, deputy secretary, Office of Oil and Gas Management at the Department of Environment Protection, Pennsylvania, in Pittsburgh about groundwater contamination. Scott’s explanation was that most contamination is because of leakages in the temporary waste pits. Besides, many shallow gas layers exist above Marcellus; in case of poorly secured wells, methane from these layers can get into the groundwater. Scott also believed that failure of casing is not a certainty, it can be fixed with better design and implementation.

Army veteran Dick Martin maps shale gas wells in the forests of Pennsylvania to raise awareness of their ill effects (Photographs: Chandra Bhushan)

Treatment and safe disposal of wastewater is also a major challenge. Between 10 and 50 per cent of the fracturing fluid pumped in the wells returns as flowback over a period of time. Then there is some amount of highly polluted moisture that comes out with the gas. These effluents contain chemicals used in fracking and metals, minerals and hydrocarbons leached from the reservoir rock. In some reservoirs radioactive minerals are also released. Such waste has to be disposed of in radioactive waste facilities. In Marcellus wells in Pennsylvania, the flowback water is so polluted that it has salt contents and chemical oxygen demand levels nearly 100 times the standard for treated industrial effluent in India.

Currently, wastewater from shale wells is either being pumped in deep injection wells or treated in dedicated plants. But deep injection wells are now being linked to the increased frequency of earthquakes. One hypothesis is that the wastewater lubricates fault lines, causing them to slip.

ABC of shale gas

What is shale gas?

Shale gas is natural gas contained within a commonly occurring rock called shale. Shale rocks are characterised by low permeability, so gas flows through them with more difficulty than through a conventional gas reservoir. Shale gas resources are also less concentrated. Compared to conventional gas, shale wells have short lives and developing a shale field requires drilling many holes over a short period. Shale gas is part of unconventional gas resources that have traditionally been considered difficult or costly to produce. These resources were known for decades but it is only due to recent technological developments, mainly horizontal drilling and hydraulic fracturing, that they are now being recognised as an important source of energy.

How is it produced?

After a patchof land is cleared, a hole, some 2000-3000 m deep, is dug vertically till it reaches the shale rocks. Steel tubes called casings are inserted and cemented in the hole to isolate the well from the surrounding rocks and aquifers. Now horizontal holes ranging from 1,000-3,000 m are dug to access the rocks at various points. Next step is to fracture the rocks to free the gas trapped within. For this water mixed with sand and chemicals is pumped into the ground at high pressure to force it through the perforations. This creates cracks in underground rocks. Hydraulic fracturing of rocks is also called fracking. Sand holds the cracks open, allowing the gas to flow into the bore well.

Given the length of horizontal wells, hydraulic fracturing is often conducted in 10-20 stages, where each stage focuses on a limited linear section and may be repeated numerous times. This multi-stage fracturing requires large volumes of water. A standard single-stage hydraulic fracturing may pump down several hundred cubic metres of water together with proppant and a mixture of chemical additives. In multi-stages the total volume of water used might reach up to 20,000 cubic metres per well and the amount of proppant up to 4,000 tonnes.

Some of the fracturing fluid injected into the well will return to the surface along with water that occurs naturally in the rocks. This is brought to the surface, collected, treated and reused or disposed of. Along with this, natural gas is also released, which is collected and treated.

Where is it found and how much?

International energyAgency estimates that the remaining technically recoverable resources of unconventional gas worldwide are similar in size to the remaining conventional gas resources. Advanced Resources International, Inc. (ARI), a consultancy firm, did the most comprehensive assessment of shale gas for the US Energy Information Administration (EIA).

It estimated the shale gas and shale oil resource in 26 regions consisting of 41 countries. According to the assessment, 7,795 trillion cubic feet of technically recoverable shale gas resources exist. Two-thirds of these are concentrated in six countries–USA, China, Argentina, Algeria, Canada and Mexico. The top 10 countries account for over 80 per cent of the currently assessed resources.

Why the interest in shale gas?

The global energy mix, in the absence of a strong climate policy, is likely to remain highly fossil fuel-dependent. According to the International Energy Agency (IEA), even in 2035 about 75 per cent of the energy demand will be met by fossil fuels. But within the fossil fuels, IEA predicts, the share of coal and oil will reduce and that of gas, which is comparatively cleaner, will increase in the next 20 years under the pressure to curb local pollution and greenhouse gases. The global demand for gas can increase by 50 per cent by 2035 compared to the 2010 level. The increase in gas demand will make many large countries increasingly import-dependent. China’s dependence on imported gas is likely to increase to 40 per cent by 2035; India’s to 45 per cent and the European Union’s to more than 80 per cent.

Much of the shale resource exists in countries with limited endowments of conventional oil and gas supplies, such as South Africa, Jordan and Chile; or in the countries which are net gas importers and face increasing import dependency, such as the US and China; or in regions where conventional hydrocarbon resources have largely been depleted, such as Europe. The exploitation of shale gas is, therefore, likely to reduce prices and import dependencies of countries for natural gas.


Big fight in Pennsylvania

After my visit to Loyalsock State Forest, I went to see fracking in the countryside. In Washington county, which has close to 1,000 operating wells, I saw fracking taking place everywhere, even next to people’s houses.

In McMurray, I met Raina Rippel and Jill Kriesky, both working for South West Environmental Health Project (SWEHP). The project is monitoring pollution and people’s health near the wells in Washington county. Its data shows big spikes in air pollutants like volatile organic compounds, PM 2.5 and formaldehyde, many times the standards, around the well sites at night. These pollutants have been linked with cancer. Rippel’s theory is that the spike is because of inversion which is common in nights in Washington county. As most wells are located in the valley, pollutants get accumulated in the night.

“There is a clear linkage between fracking and ill health of the people living nearby”

Raina Rippel, South West Environmental Health Project, McMurray
SWEHP is finding that those living next to fracking sites are more likely to have respiratory, neurological and stress-related disorders. People in the county have started going to courts on health issues. However, to hush up the matter companies are doing out-of-court settlement with people on the condition that they do not disclose health issues to anyone.

Kriesky says the respiratory illnesses can be linked to the elevated levels of air pollution, but neurological and anxiety-related disorders could be because of many factors, including fights within the community over shale gas development.

Shale gas has divided communities in rural Pennsylvania. A section of the community—landowners and people with mineral rights in split estates—has benefitted from the shale gas boom. Companies in Pennsylvania pay $1,000-4,000 per acre (0.4 hectare) to landowners for getting the right to drill. Landowners also get 10-12 per cent of the value of gas production minus the expenses as royalty. This has made many landowners millionaires.

Then there are those living next to the well sites that either don’t have gas reserves under their land or have only the surface right of the land. These people have not benefitted. On top of it, a law passed by the Pennsylvania government called Act 13 gives the industry the power to acquire private property for drilling. The industry does not even have to notify any town government of leases it has acquired or how it wants to use the leased land. This has made people with assets quite vulnerable.

“Due process and environmental rights are part of our Constitution. No one can deny these rights to us”

Dave Ball (left) and Brian Copolla, Litigants against Act 13 of Pennsylvania
Act 13 also gave the industry an instrument for arm twisting local bodies to revise their laws to allow fracking anywhere. It is called impact fee, which is charged on every well drilled. Between 2011 and 2013 the impact fee brought in $630 million to Pennsylvania. Sixty per cent of this revenue goes to counties and municipalities hosting wells. In 2013, Washington county got $6.1 million as its share. These are big amounts for local authorities. Most cannot afford to refuse the money.

However, a few local bodies and citizens sued Pennsylvania state for overriding the rights of the local bodies to write zoning laws and debar oil and gas drilling if it did not fit the land use pattern. I met two of the litigants, Dave Ball and Brian Copolla.

Ball has been the elected official from the Peters township since 2006. His is a residential township of 25,000 people who do not want fracking. So far no company has proposed fracking there, but people are apprehensive because the township is surrounded by shale development. Copolla was the elected official from the Robinson township. It was the first town in Pennsylvania which allowed fracking in 2007. Within three years a major spill happened. Soil and many drinking water wells were contaminated. Copolla then decided to stop fracking and became a petitioner in the Act 13 case.

In the very beginning of our meeting, both of them made it clear that they are not against fracking. They oppose it where it infringes on the rights of the people. It was in this context that Ball, Copolla and seven other municipalities sued Pennsylvania state because Act 13 violated the “due process rights” of the local bodies. Due process rights means not to harm one’s neighbours due to one’s activities. Local bodies have used these rights to zone their areas into distinct land uses—residential, commercial and industrial.

A typical shale pad in Loyalsock State Forest in Pennsylvania looks similar to a conventional gas well but has a bigger ecological footprint

The case went up to the Supreme Court of Pennsylvania. The court struck down provisions that allowed oil and gas development in all zoning areas. The shale gas industry is now saying that it is not an industry and hence does not have to be restricted to the industrial zone; it can come anywhere. Most importantly, since only about 50 per cent of Pennsylvania has some sort of zoning, the remaining 50 per cent is open for exploitation. So, though Ball, Copolla and co-plaintiffs won a major constitutional battle, the shale gas development in Pennsylvania continues unabated.

But that is not the case with Pennsylvania’s neighbour, New York.

Moratorium in New York 

I went to Ithaca to meet academicians, activists and politicians who had used every trick in the book to stop shale gas exploitation in their state.

New York state has a history of drilling for conventional oil and gas. But somehow a lot of New York citizens oppose shale drilling. To understand this, I met Karen Edelstein from FracTracker Alliance. It is an informal alliance that promotes transparency and information disclosure around oil and gas industry. According to Edelstein, people are opposed to shale gas because of pollution; many have opposed it due to climate change. Those who are opposed are in big cities like New York, Ithaca and Syracuse that have less shale gas potential. New York is especially worried because its source of water is 130 km away in areas with shale gas potential. New Yorkers have protected this watershed for a long time, even by paying landowners to conserve the watershed.

“Over the 10- 20 years’ time frame shale gas is worse than coal in terms of climate impacts”

Tony Ingraffea, Emeritus, Cornell University
Counties close to Pennsylvania, however, support fracking. These are agricultural communities and landowners here can get as much as $12,000 per hectare by leasing land for gas drilling. These people are very angry about the moratorium in the state on shale gas drilling. So angry, in fact, that 15 towns have threatened to secede from New York and join neighbouring Pennsylvania where fracking is allowed.

About seven years ago, the industry went around New York state telling people that fracking for shale gas was similar to conventional gas. It started leasing land and making upfront payments. The state assembly and senate passed laws that paved the way for fracking. An innocuous piece of legislation called Land Spacing Bill stipulated how much should be the spacing between shale gas wells. This de facto allowed fracking. Members of the state assembly like Barbara Lifton, a Democrat from 125 Assembly district that includes Ithaca, also voted for the bill. But lately, Lifton has become one of the most vocal critics of shale gas. I met Lifton to understand why she changed her position.

Lifton has been serving her constituency for 12 years. She has seen the entire episode up-close. According to her, the industry didn’t lobby; it silently convinced everyone that shale gas is no different than conventional gas. So, there was no debate when the bill was passed. Then people, including academicians from Cornell University, started talking about various problems with fracking. Stories of pollution and water problems from Pennsylvania started coming in. And by December 2014 re-elected governor Andrew Cuomo banned fracking in New York state.

“It is a callous and reckless industry that destroys water and affects the health of people. My assembly completely supports my position”

Barbara Lifton, Assemblywoman, New York State
Cuomo did this by releasing the findings of the six-year review by the state Department of Environment Conservation, including the study from the Department of Health. Both the departments have come to the conclusion that potential adverse impacts of fracking are “widespread” and the prospects for fracking in New York are “uncertain at best”, and the economic benefits are “far lower than originally forecasted”.

The statutory ban has made people like Tony Ingraffea very happy. Ingraffea has taught at Cornell University in the School of Civil and Environmental Engineering and is currently an emeritus at Cornell. He is an expert in fracture mechanics. His research has been used by activist groups like New Yorkers Against Fracking and politicians like Lifton to oppose fracking.

I met Ingraffea at Lifton’s office and over lunch he explained to me the intricacies of the unconventional gas and oil industry and the reasons for his opposition. Ingraffea believes shale gas is the last attempt by the fossil fuel industry to keep its hold on the energy sector.

Underestimated climate impact

Research by Ingraffea and his colleagues indicates that shale gas has far worse climate impacts than what has been assumed. Shale gas is known to have higher greenhouse gas (GHG) emissions than conventional. But in the US, shale gas is being promoted as a substitute to coal; as a “bridge fuel” to cleaner energy source till alternatives like wind and solar scaled up. However, a major debate has started on the climate performance of shale gas v coal. The central point of this controversy is how much methane is emitted during the life cycle of the shale gas and what is the global warming potential (GWP) of methane.

Methane is a more potent greenhouse gas than CO2, but has a lower half-life. GWP of methane, compared to CO2, averaged over 100 years, is 25. Averaged over 20 years, it rises to 72. Recent studies, however, peg the 20 years’ GWP of methane at 105. It is estimated that at a GWP of 105, if three per cent of shale gas production is emitted during its journey from well to burner, then shale gas losses all its GHG emissions advantage over coal (see ‘Shale gas v coal’).

New studies, including those by Ingraffea and his colleagues, are increasingly finding evidence of large emissions of methane from drilling sites. Ingraffea estimates that 3.6 per cent to 7.9 per cent of the total gas output of a shale gas well is lost through fugitive methane emissions. This would mean that “compared to coal, the footprint of shale gas is at least 20 per cent greater and perhaps more than twice as great on the 20-year horizon”.

Studies in the US are also projecting that Shale gas may also stymie the growth of the renewable energy sector for decades, thereby further jeopardising the fight against climate change.

Uncertain and speculative

Other reasons also turn people like Ingraffea against shale gas. Shale gas reserves are difficult to estimate. Most experts believe that the estimates put out by the US shale industry are speculative. In 70-80 per cent wells they drill, they are finding far less gas than estimated. A majority of wells are also depleting very fast; 70 per cent of the total gas is produced in the first two years. It is estimated that the industry in the US has to drill 5,000 to 10,000 wells every year just to maintain the existing production. These are the reasons most US shale gas companies are not profitable.

“We have a gas revolution; we have not yet established if we have a sustainable gas revolution”

Charles Ebinger, Brookings Institution
Shale gas companies in the US are surviving on junk bonds and investments from overseas. It is estimated that companies associated with the oil and gas sector now account for close to 20 per cent of all high-yield (junk) bonds of the US. Companies have leased lots of land and are showing the “value” of gas underground as an asset. These companies are selling shares to companies in China, India and Japan. They are using part of this money to buy more acreage and the cycle continues.

By the time I left Ithaca, I was convinced that shale gas in the US is bad for environment; bad for fight against climate change and will make it impossible for the US to start transitioning towards a low-carbon economy. As the US is the key for an ambitious goal action on climate change, slack on its part means other countries too would refrain from taking ambitious action.

But New York does not decide the fate of the US; Washington does. So, my last stop was Washington to understand its policies and the politics.

Washington politics

For Washington, shale gas is a reality. Even for the most diehard environmentalist it is afait accompli. The key issues in the minds of most are prices, sustainability of supply and, most importantly, environment regulations. A big debate is raging on who should regulate what, and what should be regulated without harming the industry.

The oil and gas sector in the US enjoys many exemptions under federal laws. For instance, hazardous wastes from the sector are not considered hazardous under federal laws and fracking has been excluded from the definition of disposal wells, except if they use diesel. This has been termed the Halliburton loophole because former vice-president Dick Cheney who used to head Halliburton, the largest technology and service provider to the shale gas industry, pushed this exemption. So, no federal permit is required to drill shale wells. Shale gas is largely regulated by the state Environment Protection Agencies (EPAs). But state EPAs are not equipped to deal with the scale and pace of development. They are now catching up.

Boards put up by shale gas companies to mark their territory. Under Act 13 of Pennsylvania companies can acquire any land for drilling

I met Alan Krupnick, who works at Resources for the Future’s Center for Energy and Climate Economics. Krupnick has worked extensively on shale gas regulations at the state level. His work documents huge variations in regulations from state to state. For instance, some allow treated wastes to be discharged into surface water, some allow evaporation pits, and some allow wastewater to be used for “land treatments” such as ice and dust control or road stabilisation. In general, states like North Dakota and Wyoming have relaxed regulations whereas states like New York and Colorado have strict regulations. Pennsylvania and Texas fall in between.

Krupnick’s study also found lots of gaps in the regulation such as handling of toxic wastes, closing down wells and reclamation of well pad areas. For example, the current bond for the closure is just $10,000 per well, whereas the cost can be at least $100,000. This is a big incentive for companies to run away without proper closure. Krupnick believes fracking can be done safely and risks can be reduced through appropriate regulations.

What is an appropriate regulation is something that the US Environmental Protection Agency (USEPA) has started looking at carefully.

USEPA is not happy with the Halliburton loophole, which curtailed its powers to act against the industry. It is now using existing regulations and directions from Congress to go around the loophole and put in place nationwide regulations. For instance, it is using New Source Performance Standards (NSPS) and National Emission Standards for Hazardous Air Pollutants (NESHAP), both under the Clean Air Act, to control emissions of volatile air pollutants.

Shale gas export: economics and politics

Today the US is ready to export gas, thanks to the shale gas revolution. The industry is eager, but the Congress has put a moratorium on exports. The price of gas in the US is about $3.0 per million British thermal units (MMBtu). At this price, US companies will not be able to sustain their business. They are, therefore, looking for exports to Asia where the prices are high. For comparison, India buys LNG from Qatar at $13.0/MMBtu. US companies have also signed long-term contracts with Japan and India.

Many experts believe that US companies have a window of opportunity to export gas to Asia till 2020 at $12/MMBtu. After 2020, Australia, Papua New Guinea and East Africa will start supplying gas and compete with the US. Countries like China and India will also drill for gas. Besides, in India and China, coal will compete with gas in the electricity sector. The only way the imported LNG will remain viable is if a carbon tax is put on coal. The question, one is forced to ask is: does the US anti-coal campaign in Asia has something to do with exporting shale gas?


I was hosted by Anna Phillips, programme manager for USEPA office of international and tribal affairs. Phillips had invited her colleagues to brief me on the initiatives they are taking to reduce pollution from shale gas operations.

Bruce Moore, who works at the Office of Air and Radiation, briefed me about the air pollution norms. Moore explained to me the requirement under the law to review NSPS and NESHAP every eight years to determine if technology advances warrant updating the standards. USEPA has used this review as an opportunity to tighten norms for shale wells. Under the new rule, from January 1, 2015, operators of new as well as existing wells are required to install equipments to capture gas and condensate that come up with flowback.

Although the targets of the rule are volatile organic compounds and hazardous air pollutants, powerful greenhouse gas methane will also be captured, thereby reducing climate impacts.

USEPA is also preparing to release the results of a major study on the impacts of fracking on drinking water resources. This, it is doing at the behest of Congress. The final report is likely to be used to prepare new federal regulations. However, the most contentious issue is the disclosure and regulation of chemicals used in fracking.

Spotlight on fracking chemicals

It is estimated that more than 90 per cent of the frack fluid is water and the other 10 per cent is a mix of chemicals, additives and sand. According to a 2011 congressional report, frack fluids contained 29 chemicals that are known or possible human carcinogens, regulated under the Safe Drinking Water Act, or listed as hazardous air pollutants under the Clean Air Act. Highly toxic benzene, toluene, xylene, and ethylbenzene are also used. However, all this information is guesstimate. No one knows, other than the industry, what exactly is the composition of frack fluid. And this is again because of a legal loophole.

The federal Safe Drinking Water Act authorises states to regulate underground fluid injection. In 2005, however, Congress amended the Act to exclude fracturing fluids. This has meant that companies are not required to disclose what chemicals they are pumping underground. To overcome this, many states have introduced legislation on disclosure. However, the level of details to be disclosed varies significantly. Not all states require disclosure of all chemicals. Hardly any state regulates chemicals beyond mere disclosure.

Anti-fracking protests in New York led to a moratorium on shale gas drilling in the state (Courtesy: news .vice.com)

There has been a persistent demand from environmental groups for a federal law to regulate fracking chemicals. But the industry is reluctant. I was curious to know why.

I met Chris Benscher, manager of government affairs at Halliburton, which has 70 per cent of the US shale gas service market share. As Benscher pointed out to me, Halliburton fracks a well every two minutes.

Benscher entered the meeting room with a champagne bottle, the significance of which he revealed later. He was forthright about Halliburton’s position on various issues. Halliburton believes in climate change, Benscher explained, but also believes that fossil fuels like shale gas are bridge fuel and technology like carbon capture and sequestration are important to exploit fossil fuels and save the climate. On regulating shale gas, Halliburton maintains federal government is not the appropriate level of government; states look after land and natural resources, therefore, they should regulate it.

Benscher was most critical of USEPA trying to regulate fracking chemicals. He believed that fracking chemicals are proprietary products disclosure of which would harm the industry. He pointed to the champagne bottle and told me that it contains a proprietary fracking fluid, named CleanStim, made from food industry ingredients. Halliburton executives are known to take a sip of this fluid in conferences to make the point that fracking fluids can be made non-toxic. When I asked Benscher about the extent to which his “organic” fluid was used by the industry, he declined to give exact figures. However, one expert told me that “CleanStim is still in the bottle and not in the field”.

Halliburton’s position on disclosure is, rejected by many think tanks, environmental groups and even members of the US Congress. USEPA has indicated that it will require disclosure under the Toxic Substances Control Act.

At I was winding up my trip, I went to meet Charles Ebinger, who works in the Energy Security and Climate Initiative at Brookings Institution. Charles has special expertise in South Asia. “Have regulation and regulatory institutions in place before the industry takes off. Don’t do the mistakes we did.” This was his last advice to me.

Shale tempts India

The world over, interest in natural gas is growing because it is the cleanest burning fossil fuel. The global consumption of natural gas has increased by 30 per cent in the past 10 years. The International Energy Agency (IEA) has even predicted a golden age for natural gas in which the global gas demand rises by more than 50 per cent between 2010 and 2035, and natural gas overtakes coal to become the second-largest primary energy source after oil. IEA’s golden age for natural gas is based on the assumption of unlocking the world’s vast resources of shale gas.

Natural gas is a scarce commodity in India. The gap between demand and supply of natural gas is about 40 per cent. On top of this, India imports about 30 per cent of its natural gas consumption at a very high price. India will face a shortfall of more than 3.8 tcf of natural gas by 2015-16, up from 3.2 tcf in 2013-14, according to the petroleum ministry. Short supply and high prices of natural gas have led to significant negative environmental and social impacts in the country.

India is not able to provide natural gas for cooking to a large proportion of its population. Only about 12 per cent of its rural households and 65 per cent of the urban households use liquefied petroleum gas as a main source of cooking energy. Indoor air pollution from traditional cooking fuels such as firewood is leading to large-scale premature deaths and diseases.

Close to 80 per cent of all households in India use traditional cooking fuels such as firewood. This is leading to largescale premature deaths and diseases (Photo: Vikas Choudhary)

India is not able to supply natural gas to the urban transport sector either. Thirteen of the world’s top 20 air polluted cities are in India. Gas can play a big role in reducing urban air pollution. Gas power plants of the combined capacity of 10,000 MW are idle due to gas shortage. Adequate supply of gas to these plants can reduce coal consumption in India significantly, thereby reducing both local pollution and carbon emissions.

India is, therefore, looking for an affordable and secure supply of natural gas. It is planning to bring gas from Central Asia, the Gulf countries as well as from the US. It is also looking to explore shale gas.

Shale gas resource in India is not very high. The present technically recoverable shale gas resource is about 100 tcf, spread over four on-land sedimentary basins, namely Cambay in Gujarat; Krishna-Godavari in Andhra Pradesh; Cauvery in Tamil Nadu; and Damodar basin in Jharkhand and West Bengal. These resources are sufficient to meet India’s gas demand at the current level for about 25 years. However, India has a vast sedimentary area and many more shale gas basins can be found.

So far the development of shale gas in India is limited to drilling of a few exploratory wells in Jambusar (Gujarat), Durgapur (West Bengal) and Hazaribagh (Jharkhand). Initial results indicate that shale gas basins in India are also not as prolific as those in the US. Besides, since India does not have a good service sector for the oil and gas industry as in the US, shale gas extraction will be difficult and more expensive.

In 2013, India finalised its policy for exploration and exploitation of shale gas. The policy has adopted a cautionary approach and has allowed only national oil companies to carry out exploration and exploitation; private companies are not allowed. But this could change very quickly as has happened in the US.

What should India do?

With higher population density, lower per capita water resources and higher proportion of arable and forest land, the impacts of fracking on the ecosystems and communities in India would be higher than in the US. But the question is how high.

It is obvious that shale gas is more damaging than conventional gas, but is it more damaging than coal? From my travel in the US and familiarity with coal mining practices in India, I would prefer shale gas any day to coal. Shale gas development has lower impacts on the local environment compared to coal mines, including impacts on water and especially on the local community. The only rider is that we should not do the mistakes that the US has done like not putting in place stringent environmental norms and practices.

I also believe that shale gas is not a solution for climate change. It is not a “bridge fuel” between coal and renewable energy. On climate change the world needs to take action in the next 20-30 years and methane is hugely damaging to climate over a 20-year period. So, should India go for shale gas?

Coal mining in India has devastated large tracts of land and forests, and destroyed groundwater, rivers and communities (Sugandh Juneja)

I could take a moral high ground and say that India should not go for shale gas. But, considering the scarcity of gas and benefits it can provide to vast sections of the population, including the health of women and improved air quality in cities, this would be a hypocritical position, especially in light of the large-scale shale gas use in the US and potentially in China, Australia and other countries that have more responsibility towards climate change. I, therefore, think that India should go ahead with shale gas development but cautiously.

India should be clear why it wants to develop shale gas. India should do it to meet its essential gas demand, but not portray it as a solution to climate change as the US is doing. India, therefore, needs to strike a balance between its local imperatives and its responsibility towards global environmental challenges.

At the global level, India should work with other countries to set national and global goals for renewable energy and energy efficiency so that we do not lose focus on climate change.

At the local and national level, we should put the following environmental and social safeguards without any compromise:

Undertake a detailed investigation of basins to understand issues like water requirements; quality and quantity of wastewater generation; characteristics of wastes and air emissions. This information should be out in the public domain for taking a democratic decision.

The existing environmental rules and regulations on natural gas are not suitable for shale gas. India should draft new stringent rules and regulations covering the life cycle of shale gas development. This should include requirements for a detailed environmental impact assessment, stringent water use and pollution control standards, standards for air pollution (including methane) and safe disposal of wastes.

Have a “no-go” policy for shale gas development in areas with high ecological value, important watershed or areas with water stress.

Put in place a highly advanced waste management infrastructure to deal with toxic and potentially radioactive wastes. Till we develop these, we should put a moratorium on shale gas development.

Consent of the community, regular consultation with them and information disclosure are very important, so is sharing benefits with them.

The question is not whether India should go ahead with shale exploitation but how and where. India will have to reinvent its regulatory regime.




[Revision] Chemistry Part-3: Hydrogen Economy, Hard Water types & treatment, Hydrogen Peroxide, Acid, Base, Salt[Mrunal]

Prologue

  • Continuing on…This article contains revision note out of Chapter 6, 7, 8 and 9 of Chemistry Class11.
  • As such nothing much from 6 to 8 because they deal with technical stuff in thermodynamics, redox equation etc.

Water: Importance in Biosphere

  • Water plays a key role in the biosphere because compared to other liquids, water has a higher specific heat, thermal conductivity, surface tension, dipole moment and dielectric constant.
  • Water moderates climate and body temperature because of its high heat of vaporisation and heat capacity are responsible.
  • Water is an excellent solvent for transportation of ions and molecules for plant-animal metabolism.
  • ice cube floats on water because Ice’s density is less than that of water..
  • In winter season ice formed on the surface of a lake gives thermal insulation & helps aquatic life to survive.

POSSIBLE MCQ: ASCENDING DESCENDING ORDER OF WATER SOURCES)

Water: Chemical Properties

  1. Water can dissolve many salts, particularly in large quantity, makes it hard and hazardous for industrial use.
  2. The polar nature of water makes it: (a) a very good solvent for ionic and partially ionic compounds; (b) to act as an amphoteric (acid as well as base) substance; and (c) to form hydrates of different types.
  • Amphoteric Nature: Water can act as an acid as well as a base.
  • Extensive hydrogen bonding between water molecules= high freezing point, high boiling point. And Due to this hydrogen bonding with polar molecules, even covalent compounds like alcohol and carbohydrates dissolve in water.
  • Rain water is almost pure (except some dissolved gases from the atmosphere)
  • When rain water flows through earth surface, it dissolves many salts and becomes hard.
  • Soft water: it doesn’t have calcium and magnesium’s soluble salts. Soft water gives lather with soap easily.

Hard Water: Properties

  • Hard water does not give lather with soap.
  • Presence of calcium and magnesium salts in the form of hydrogencarbonate, chloride and sulphate in water makes water ‘hard’.
  • Soap containing sodium stearate reacts with hard water to precipitate out Ca/Mg stearate.
  • Hard water forms scum/precipitate with soap, so it is unsuitable for laundry.
  • This salt deposit also decreases efficiency of boiler.

Hard water: Types & Treatment

  • Hardness of water is of two types: (i) temporary hardness, and (ii) permanent hardness.
Temporary hardness Permanent Hardness
Due to the presence of magnesium and calcium hydrogen- carbonates. Due to presence of presence of soluble salts of magnesium and calcium in the form of chlorides and sulphates in water.
Removed by following methods:

  1. Boiling: to convert soluble carbonates into insoluble carbonates, then they’re filtered off.
  2. Clark’s method: lime added to water. It’ll precipitate out calcium carbonate and magnesium hydroxid. Then it is filtered off.
Not possible to remove this hardness by boiling. But following methods will work

  1. Treatment with washing soda (sodium carbonate): It’ll form insoluble carbonates that can be filtered off.
  2. Calgon’s method: add Sodium hexameta- phosphate. ‘calgon’ is the commercial name of this chemical.
  3. Ion-exchange method using zeolite/permutit (Hydrated sodium aluminium silicate)
  4. Synthetic resin ion exchangers.

Hydrogen Peroxide (H2O2)

3 isotopes of Hydrogen: same proton but different neutron numbers

Isotop proton neutron rarity
protium 1 0 99.985% hydrogen is like this
Deuterium (heavy hydrogen) 1 1 0.015%
Tritium (radioactive) 1 2 trace amount in earth
Hydrogen paroxide: chemical properties
  1. Pollution control treatment of domestic and industrial effluents.
  2. Properties: Colourless-pale blue liquid. Acts as an oxidising as well as reducing agent in both acidic and alkaline media.
  3. H2O2 decomposes slowly on exposure to light hence stored in dark.
  4. In metal surfaces or traces of alkali (present in glass containers), H2O2 reaction is catalysed. Therefore it is stored in wax-lined glass or plastic vessels in dark.
  5. Urea can be added as a stabiliser.
  6. H2O2 must be kept away from dust because dust can induce explosive decomposition of the compound.

H2O2: Uses

  1. Hair bleach, bleaching agent for textiles, paper pulp, leather, oils, fats, etc.
  2. Mild disinfectant, antiseptic (perhydrol).
  3. Sodium based detergents.
  4. Synthesis of pharmaceuticals (cephalosporin, hydroquinone), tartaric acid and certain food products
  5. Used in Environmental (Green) Chemistry- for pollution control treatment of domestic and industrial effluents, oxidation of cyanides, restoration of aerobic conditions to sewage wastes, etc.

Water gas / Syngas

  • Water gas/syngas/synthesis gas is the mixture of CO and H2.
  • It is further used for the synthesis of hydrocarbons such as methanol.
  • Syngas is produced from sewage, saw-dust, scrap wood, newspapers etc.
  • Coal gasification is the process of producing ‘syngas’ from coal.

Dihydrogen Properties and uses

  • Dihydrogen is a colourless, odourless, tasteless, combustible gas.
  • Prepared by (1) water-gas shift reaction from petrochemicals (2) electrolysis of brine.
  • Lighter than air and insoluble in water.
  • Dihydrogen =>Synthesis of ammonia =>mfg. of nitric acid and nitrogenous fertilizers.
  • hydrogenation of polyunsaturated vegetable oils like soyabean, cotton seeds etc=> Vanaspati Ghee.
  • Manufacture of methanol and other bulk organic chemicals.
  • Mfg. of metal hydrides, hydrogen chloride.
  • To reduce heavy metal oxides to metal
  • Atomic hydrogen and oxy-hydrogen torches used for cutting and welding purposes. They can generate the temperature of 4000 K.
  • Dihydrogen fuel cells = electrical energy and rocket fuel.

Hydrogen Economy: basis principle

  • use di-hydrogen to store and transport energy.
  • Energy is transmitted in the form of dihydrogen and not as electric power.
  • 2005: India launched pilot project to use dihydrogen as fuel for running automobiles.
  • Initially 5% dihydrogen has been mixed in CNG for use in four-wheeler vehicles. It’ll be increased gradually.
  • dihydrogen can release 3x times more energy than petrol
  • It produces less pollutants than than petrol.
  • Dihydrogen’s pollutant is called “oxides of dinitrogen”. We can minimize its emission by adding water in the cylinder.

Limitations of Dihydrogen fuel

  • Its cylinder weight 30 times more than petrol tank.
  • Liquification requires cooling to 20K. This Is very expensive.

Acid, Base, Salts

what’s the difference?

Acid Base
turn blue litmus paper into red turn red litmus paper blue
Acid accepts electron pair Donates pair of electrons
“acid” word derived from a latin word “acidus” meaning sour. Bases are known to , taste bitter and feel soapy. Common example: washing soda.
  • They liberate dihydrogen on reacting with metal
  • Arrhenius theory, acids are substances that dissociates in water to give hydrogen ions H + (aq) and bases are substances that produce hydroxyl ions OH – (aq)
Acids Bases

POSSIBLE MCQ: ASCENDING-DESCENDING ORDER
Examples of acids

Hydrochloric acid Gastric juice essential for digestions
Acetic acid main constituent of vinegar.
Lemon juice citric acid
Orange Juice ascorbic acids
Tamarind paste tartaric acid

Salts

  • When acids and bases are mixed in the right proportion they react and give salts.
  • Example: sodium chloride, barium sulphate, sodium nitrate.
  • hydrochloric acid + sodium hydroxide.= Salt (Sodium chloride)

PH

  • pH scale: Hydronium ion concentration in molarity – that is expressed on a logarithmic scale known as the pH scale.
  • Buffer Solutions: These solutions resist change in pH in presence of acid or alkali.
  • The pH of a solution is defined as the negative logarithm to base 10 of the activity
  • PH Measurement has biological and cosmetic applications.
  • Now-a-days pH paper is available with four strips on it. They can determine PH with an accuracy of ~0.5.
  • pH meter is a device that measures the pH-dependent electrical potential of the test solution within 0.001 precision.
  • pH meters of the size of a writing pen are now available in the market
PH Scale

Extensive vs. Intensive properties

Thermodynamics related properties

extensive properties intensive properties
Depends on quantity of the matter in system Those properties which do not depend on the quantity or size of matter present
Examples: mass, volume, internal energy, enthalpy, heat capacity, etc. Temperature, pressure, density
Daniel Cell

DANIELL CELL: ELECTRONS PRODUCED AT THE ANODE DUE TO OXIDATION OF ZN TRAVEL THROUGH THE EXTERNAL CIRCUIT TO THE CATHODE WHERE THESE REDUCE THE COPPER IONS.
Misc Terms

Oxidation Loss of electron(s) by any species. 20% of atmosphere is dioxygen, hence many elements combine with it and to form of their oxides.
Reduction Gain of electron(s) by any species.
Oxidising agent Acceptor of electron(s).
Reducing agent Donor of electron(s).
Entropy It is a measure of disorder or randomness. The greater the disorder in an isolated system, the higher is the entropy.
Heavy water
  • Prepared by (1) water electrolysis (2) by-product in some fertilizer industries
  • Used as Moderator in nuclear reactors.
Svante Arrhenius (Sweden)
  • Gave the Arrhenius acid theory.
  • He was the first to discuss the ‘greenhouse effect’ calling by that name. He received Nobel Prize in Chemistry in 1903 for his theory of electrolytic dissociation and its use in the development of chemistry
Faraday (London)
  • worked on electricity and magnetism
  • Established modern field theory.

Possible MCQs

  1. match the following: (1) methods to remove hardness of water vs. chemical principle (2) isotopes of hydrogen (3) chemical vs. its uses (4) food item vs. acid component
  2. assertion reasoning related to (1) water’s importance in biosphere (2) why water used in dihydrogen engine
  3. which of the following statements are correct about (1) ice (2) hard water and its treatment methods (3) hydrogen
  4. Arrange following xyz items in their ascending / descending order of PH.



Crux of The HIndu (Science and Technology) April- June 2015

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BS+ET+TOI 05-08-2015

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Indian-Express-06-August-2015




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6 August The Hindu ePaper

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